Research on the Influence of Polyacrylonitrile Precursor on the Properties of Carbon Fibers and Pultruded Composite Materials
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Keywords

Polyacrylonitrile precursor
Carbon fiber
Pultrusion
Composites
Performance effects

DOI

10.26689/jwa.v9i4.11839

Submitted : 2025-08-09
Accepted : 2025-08-24
Published : 2025-09-08

Abstract

Polyacrylonitrile (PAN) precursor is a core precursor for the preparation of high-performance carbon fibers. Its unique chemical structure and physical properties directly contributes to the microstructure and mechanical properties of carbon fibers, and therefore affect the overall performance of pultruded composites. This study systematically investigated the influence of PAN precursor properties on the degree of graphitization, surface morphology and mechanical properties of carbon fibers by regulating the molecular weight distribution, stretching ratio and impurity content of PAN precursor, and analyzed the mechanism of action of carbon fiber properties on the interfacial bonding strength and tensile/bending properties of composites in combination with the pultrusion process. The results showed that when the filament stretchability was increased to 4.5 times, the axial orientation of carbon fibers increased by 18% and the tensile strength reached 520 MPa; Filaments with impurity content below 0.3% increase carbon fiber yield by 5.2% and interlaminar shear strength of composites by 23%. This study provides a theoretical basis for raw material screening and process optimization of high-performance carbon fibers and their composites.

References

Ge G, Wang L, Gou P, 2025, Analysis of the Relationship Between the Viscosity Increase of PAN Spinning Solution and the Properties of Precursor and Carbon Fiber, High Technology Fibers & Applications, 50(02): 51–57.

Lan Z, Zhou H, Wang Y, et al., 2025, The Mechanism of Air Pressure in the Pre-oxidation Process of Polyacrylonitrile Precursor, Polymer Materials Science and Engineering, 41(02): 78–86.

Su B, 2024, Preparation and Properties Study of Polyacrylonitrile-Based Nanofiber Composites, thesis, Inner Mongolia Agricultural University.

Li X, Han X, Zhao H, et al., 2024, Research Progress on Green Adsorption of Polyacrylonitrile-Based Carbon Fibers in Water Treatment, Aging and Application of Synthetic Materials, 53(05): 81–83.

Wang Z, Zhong J, Zhou Z, et al., 2024, Study on the Effect of Lignin Structure on Mechanical Properties of Polyacrylonitrile/Ground Wood Lignin-Based Carbon Fibers, Chemical and Biological Engineering, 41(10): 44–49 + 63.

A Spinning Assembly for Large Filament Carbon Fiber Precursor and a Method for Preparing Polyacrylonitrile-Based Large Filament Carbon Fiber Precursor, 2024, Qilu Petrochemical Industry, 52(03): 239.

Preparation Method of a Low Grain Size Polyacrylonitrile Precursor, 2024, High Technology Fibers & Applications, 49(04): 76.

Qin Q, Xu L, Chen T, et al., 2024, Research on the Preparation Process of High Performance Polyacrylonitrile-Based Carbon Fiber Precursor, Synthetic Fibers, 53(08): 45–49.

Wang J, Zhao Y, Li J, et al., 2024, Research Progress on Polymerization Process of High Molecular Weight Polyacrylonitrile, Synthesis Technology & Application, 39(02): 28–32.

Gu L, Fan B, Sun Q, et al., 2024, Analysis of Influencing Factors of Oxygen Content Detection in Polyacrylonitrile-Based Carbon Fiber Precursor, Synthetic Fibers, 53(06): 54–55.

Xu J, 2024, Preparation and Performance Study of Oiling Agent for High Heat Resistance Carbon Fiber Precursor, thesis, Changzhou University.

Yang X, 2024, The Effect of Methyl Acrylate on the Structure and Properties of Polyacrylonitrile Fibers, thesis, Jilin Institute of Chemical Technology.

A High-Performance Polyacrylonitrile-Based Carbon Fiber Precursor and Its Preparation Method and Application, 2024, High Technology Fibers & Applications, 49(02): 75.

Geng Y, Zhang K, 2023, Research on the Production Process of Polyacrylonitrile-Based Carbon Fiber Precursor, Shanxi Chemical Industry, 43(10): 16–17 + 22.

Zhang M, Gu H, Zhang S, et al., 2021, Effects of Polyacrylonitrile Precursor on the Properties of Carbon Fibers and Pultruded Composites, New Materials for Chemical Industry, 49(12): 153–157.